To provide restrictions even for administrator accounts merge the following in the registry:
Windows Registry Editor Version 5.00
[HKEY_CURRENT_USER\Software\Policies\Microsoft\Windows\Network Connections]
"NC_EnableAdminProhibits"=dword:00000001
To prohibit access to properties of a LAN connection:
Windows Registry Editor Version 5.00
[HKEY_CURRENT_USER\Software\Policies\Microsoft\Windows\Network Connections]
"NC_LanProperties"=dword:00000000
To disable the Ability to enable/disable a LAN connection:
Windows Registry Editor Version 5.00
[HKEY_CURRENT_USER\Software\Policies\Microsoft\Windows\Network Connections]
"NC_LanConnect"=dword:00000000
To prohibit TCP/IP advanced configuration:
Windows Registry Editor Version 5.00
[HKEY_CURRENT_USER\Software\Policies\Microsoft\Windows\Network Connections]
"NC_AllowAdvancedTCPIPConfig"=dword:00000000
To Prohibit access to the advanced settings item on the advanced menu:
Windows Registry Editor Version 5.00
[HKEY_CURRENT_USER\Software\Policies\Microsoft\Windows\Network Connections]
"NC_AdvancedSettings"=dword:00000000
To Prohibit access to the new connection wizard:
Windows Registry Editor Version 5.00
[HKEY_CURRENT_USER\Software\Policies\Microsoft\Windows\Network Connections]
"NC_NewConnectionWizard"=dword:00000000